hsk8te2006
15+ Year Contributor
- 182
- 1
- Jun 9, 2007
-
Ann Arbor,
Michigan
Hi Everyone,
I have a theory that I believe is scientifically sound based on chemistry and thermodynamics, but I'd like the DSM experts with experience to tell me what they think...
The ideal gas law that approximates the relationship of air temprature, volume, pressure, and amount (number of molecules) is:
PV = nRT
where, P = pressure, V = volume, n = the amount of air (the # of moles, or # molecules x avagadro's #), R is the ideal gas constant, and T = Temperature.
The volume of my engine is a constant. (I know the EV can be altered by RPM, but that won't affect this doscussion).
I can use a MBC to control the amount of pressure in the intake manifold, and therefore the pressure of the air that enters the combustion chambers. Thus, intake pressure under full throttle is a constant with a MBC. (Ignoring boost creep or spike and shitty stock turbo high RPM performance for now, as they also dont affect this discussion).
However, when ambient air temperature goes up, the temeprature of the air that enters the combustion chamber will go up as well.
Since Pressure and Volume are constants in a properly MBC'd engine, then if the Temperatrue goes up, the only way for the ideal gas law to be satisfied is if fewer molecules of air enter the engine.
That being said, unless I'm wrong, the limits of any fuel system (such as my low out put stock fuel system) is based on balancing the number of molecules of fuel with the number of molecules of air, at an appropriate AFR for safety and performance.
If I am correct so far, then the fuel system being able to deliver a set max number of molecules of fuel to the combustion chambers, should mean that attaining the stoichiometrically equivalent maximum number of air molecules would be the desired result of the maximum boost of the turbo/intake system.
Therefore, I think that in order to match up the appropriate number of air molecules to match the maximum fuel system capacity (also a number of molecules), then at a higher ambient air temeprature, a slightly higher boost level (pressure level) should compensate for the lower number of molecules present in the engine's volume due to the higher temperature.
Thus, my theory is that at a higher ambient air temperature, a slightly higher boost level may be safe and beneficial for power.
Expert opinions?
Thanks,
Jonathan
BTW... using the ideal gas law for calculations for my theory above, it means that if an appropriate boost level was 15.5psi at 90 Degrees F, then at 0 degrees F it would be equivalent to run about 10.7 PSI.
OR, if running 15 psi at 70 Degrees F, then at 30 degrees F it would be equivalent to run about 12.8 PSI.
Similarly, 25psi at 90 Degrees F would = 18.7 psi at 0 Degrees F
and
25 psi at 70 Degrees F would = 22.1 psi at 30 degrees F
I have a theory that I believe is scientifically sound based on chemistry and thermodynamics, but I'd like the DSM experts with experience to tell me what they think...
The ideal gas law that approximates the relationship of air temprature, volume, pressure, and amount (number of molecules) is:
PV = nRT
where, P = pressure, V = volume, n = the amount of air (the # of moles, or # molecules x avagadro's #), R is the ideal gas constant, and T = Temperature.
The volume of my engine is a constant. (I know the EV can be altered by RPM, but that won't affect this doscussion).
I can use a MBC to control the amount of pressure in the intake manifold, and therefore the pressure of the air that enters the combustion chambers. Thus, intake pressure under full throttle is a constant with a MBC. (Ignoring boost creep or spike and shitty stock turbo high RPM performance for now, as they also dont affect this discussion).
However, when ambient air temperature goes up, the temeprature of the air that enters the combustion chamber will go up as well.
Since Pressure and Volume are constants in a properly MBC'd engine, then if the Temperatrue goes up, the only way for the ideal gas law to be satisfied is if fewer molecules of air enter the engine.
That being said, unless I'm wrong, the limits of any fuel system (such as my low out put stock fuel system) is based on balancing the number of molecules of fuel with the number of molecules of air, at an appropriate AFR for safety and performance.
If I am correct so far, then the fuel system being able to deliver a set max number of molecules of fuel to the combustion chambers, should mean that attaining the stoichiometrically equivalent maximum number of air molecules would be the desired result of the maximum boost of the turbo/intake system.
Therefore, I think that in order to match up the appropriate number of air molecules to match the maximum fuel system capacity (also a number of molecules), then at a higher ambient air temeprature, a slightly higher boost level (pressure level) should compensate for the lower number of molecules present in the engine's volume due to the higher temperature.
Thus, my theory is that at a higher ambient air temperature, a slightly higher boost level may be safe and beneficial for power.

Expert opinions?
Thanks,
Jonathan
BTW... using the ideal gas law for calculations for my theory above, it means that if an appropriate boost level was 15.5psi at 90 Degrees F, then at 0 degrees F it would be equivalent to run about 10.7 PSI.
OR, if running 15 psi at 70 Degrees F, then at 30 degrees F it would be equivalent to run about 12.8 PSI.
Similarly, 25psi at 90 Degrees F would = 18.7 psi at 0 Degrees F
and
25 psi at 70 Degrees F would = 22.1 psi at 30 degrees F
