The "I'm A Cut-And-Paste Tool" Tread that died.

[bartels903]

A PP3 battery, commonly referred to simply as a nine-volt battery, is shaped as a rounded rectangular prism and has a nominal output of nine volts. Its nominal dimensions are 48 mm × 25 mm × 15 mm (ANSI standard 1604A). It is widely used in smoke detectors, guitar effect units, pocket radios, and as backup batteries for digital clocks and alarm clocks. However PP3 refers to the type of connection that is on top of the battery or snap. The PP3 connector (snap) consists of two connectors: one smaller circular (male) and one larger, typically either hexagonal or octagonal (female). The connectors on the battery are the same as on the connector itself -- the smaller one connects to the larger one and vice versa.


[edit] History
The PP3 appeared when portable transistorised radio receivers became common, and is still called a "transistor" battery by some manufacturers. The Energizer company claims that it introduced this battery type in 1956 [1]. It is very widely used in smoke alarms and carbon monoxide alarms.


[edit] Unconventional Uses
Placing one's tongue across the terminals will short circuit the battery and may cause a mild shock, and as such may be used as a prank or a crude test of the battery's charge. This can produce tiny amounts of chlorine gas[citation needed], which is toxic.

Additionally, placing steel wool across the terminals will cause the steel to ignite. This method of fire starting is often taught from a wilderness survival perspective, as it will catch flame even while wet.

The clips on the 9-volt battery can also be used to connect lots of 9-volt batteries in series. At least one death has been attributed to electrocution from too many 9-volt batteries connected together[citation needed]. Alternatively, one can connect two 9-volt batteries together in a short circuit. The high current and heat may lead to a fire.

Sometimes cutting open the battery yields 6 AAAA batteries. [2] (note that the comments correct the article).

An alternative construction uses 6 oval shaped button cells, or 7 cells in a rechargeable for 8.4V nomimal.


[edit] Technical specs
The battery has both the positive and negative terminals on one end. The negative terminal is fashioned into a snap fitting which mechanically and electrically connects to a mating terminal on the power connector. The power connector has a similar snap fitting on its positive terminal which mates to the battery. This makes battery polarization obvious since mechanical connection is only possible in one configuration. One problem with this style of connection is that it is very easy to connect two batteries together in a short circuit, which quickly discharges both batteries, generating heat and possibly a fire. The wiring usually uses black and red wires, red for positive.

Inside a PP3 there are ordinarily six alkaline or carbon-zinc 1.5 volt (nominal) cells arranged in series. These are either AAAA cells, or special flat, rectangular cells. The exact size of the constituent cells varies from brand to brand -- some brands are slightly longer than others -- as does the manner in which they are joined together. Some brands use soldered tabs on the battery, others press foil strips against the ends of the cells.

Very cheap versions may contain only five 1.5 volt cells. Rechargeable NiCd and NiMH batteries have various numbers of 1.2 volt cells. Lithium versions use three 3 V cells - there is a rechargeable lithium polymer version.

 

[bartels903]

Lithium batteries were first proposed by M.S. Whittingham, then at Exxon, in the 1970s. [4] Whittingham used titanium sulfide as the cathode and lithium metal as the anode.

Lithium batteries, in which metallic lithium is the anode, posed severe safety issues. As a result, lithium ion-batteries were developed, in which the anode, like the cathode, is also a material into which lithium ions insert. Lithium-ion batteries came into reality once Bell Labs developed a workable graphite anode[5] to provide an alternative to lithium metal, the lithium battery. Following groundbreaking cathode research by a team led by John Goodenough[6] (then at Oxford University, now at the University of Texas, Austin), the first commercial lithium ion battery was released by Sony in 1991. The cells utilized layered oxide chemistry, specifically lithium cobalt oxide. Used in numerous commercial applications these batteries revolutionized consumer electronics.

In 1983, Michael Thackeray and coworkers identified manganese spinel as a cathode material.[7] Spinel showed great promise, since it is a low-cost material, has good electronic and lithium ion conductivity, and possess a three dimensional structure, which gives it good structural stability. Although pure manganese spinel shows fade with cycling, this can be overcome with additional chemical modification of the material.[8] Manganese spinel is currently used in commercial cells. [9]

In 1989, Arumugam Manthiram and John Goodenough at the University of Texas at Austin showed that cathodes containing polyanions, such as sulfates, show higher voltage than oxides due to the inductive effect of the polyanion.[10] Following this, in 1996, Goodenough and coworkers discovered the electrochemical utility of the olivine material lithium iron phosphate, LiFePO4. It is an important and emerging cathode material for lithium-ion batteries due in part to its enhanced safety compared to other lithium-ion chemistries. Cells containing lithium iron phosphate cathodes have been commercialized by multiple companies, including Phostech, Valence Technology, and A123Systems.


[edit] Electrochemistry
The three participants in the electrochemical reactions in a lithium ion battery are the anode, cathode, and electrolyte.

Both the anode and cathode are materials into which lithium inserts and extracts. The process of lithium moving into the anode or cathode is refered to as insertion, and the reverse process, in which lithium moves out of the anode or cathode is referred to as extraction. When discharging of the cell, the lithium is extracted from the anode and inserted into the cathode. When charging the cell, the exact reverse process occurs: lithium is extracted from the cathode and inserted into the anode.

The anode of a conventional Li-ion cell is made from carbon, the cathode is a metal oxide, and the electrolyte is a lithium salt in an organic solvent.[citation needed]

The underlying chemical reaction that allows Li-ion cells to provide electricity is:


[citation needed]

It is important to note that lithium ions themselves are not being oxidized; rather, in a lithium-ion battery the lithium ions are transported to and from the cathode or anode, with the transition metal, Co, in LixCoO2 being oxidized from Co3+ to Co4+ during charging, and reduced from Co4+ to Co3+ during discharge

Liquid electrolytes in Li-ion batteries consist of solid lithium-salt electrolytes, such as LiPF6, LiBF4, or LiClO4, and organic solvents, such as ether. A liquid electrolyte conducts Li ions, which act as a carrier between the cathode and the anode when a battery passes an electric current through an external circuit. However, solid electrolytes and organic solvents are easily decomposed on anodes during charging, thus preventing battery activation. Nevertheless, when appropriate organic solvents are used for electrolytes, the electrolytes are decomposed and form a solid electrolyte interface at first charge that is electrically insulating and high Li-ion conducting. The interface prevents decomposition of the electrolyte after the second charge. For example, ethylene carbonate is decomposed at a relatively high voltage, 0.7 V vs. Li, and forms a dense and stable interface.[citation needed]

See uranium trioxide for some details of how the cathode works. While uranium oxides are not used in commercially made batteries, the way in which uranium oxides can reversibly insert cations is the same as the way in which the cathode in many lithium-ion cells work.[citation needed]


[edit] Advantages and disadvantages

[edit] Advantages
Lithium-ion batteries can be formed into a wide variety of shapes and sizes so as to efficiently fill available space in the devices they power.

Li-ion batteries are lighter than other equivalent secondary batteries—often much lighter. The energy is stored in these batteries through the movement of lithium ions. Lithium has the third smallest atomic mass of all the elements giving the battery a substantial saving in weight compared to batteries using much heavier metals. However, the bulk of the electrodes are effectively "housing" for the ions and add weight, and in addition "dead weight" from the electrolyte, current collectors, casing, electronics and conductivity additives reduce the charge per unit mass to little more than that of other rechargeable batteries. A key advantage of using Li-ion chemistry is the high open circuit voltage that can be obtained in comparison to aqueous batteries (such as lead acid, nickel metal hydride and nickel cadmium).[citation needed]

Li-ion batteries do not suffer from the memory effect. They also have a low self-discharge rate of approximately 5% per month, compared with over 30% per month in nickel metal hydride batteries and 10% per month in nickel cadmium batteries.

According to one manufacturer, Li-ion cells (and, accordingly, "dumb" Li-ion batteries) do not have any self-discharge in the usual meaning of this word.[11] What looks like a self-discharge in these batteries is a permanent loss of capacity, described in more detail below. On the other hand, "smart" Li-ion batteries do self-discharge, due to the small constant drain of the built-in voltage monitoring circuit. This drain is the most important source of self-discharge in these batteries.

A unique drawback of the Li-ion battery is that its life span is dependent upon aging from time of manufacturing (shelf life) regardless of whether it was charged, and not just on the number of charge/discharge cycles. So an older battery will not last as long as a new battery due solely to its age, unlike other batteries. This drawback is not widely publicised.[12]

At a 100% charge level, a typical Li-ion laptop battery that is full most of the time at 25 degrees Celsius or 77 degrees Fahrenheit will irreversibly lose approximately 20% capacity per year. However, a battery stored inside a poorly ventilated laptop may be subject to a prolonged exposure to much higher temperatures than 25 °C, which will significantly shorten its life. The capacity loss begins from the time the battery was manufactured, and occurs even when the battery is unused. Different storage temperatures produce different loss results: 6% loss at 0 °C (32 °F), 20% at 25 °C (77 °F), and 35% at 40 °C (104 °F). When stored at 40% - 60% charge level, these figures are reduced to 2%, 4%, 15% at 0, 25 and 40 degrees Celsius respectively.

As batteries age, their internal resistance rises. This causes the voltage at the terminals to drop under load, reducing the maximum current that can be drawn from them. Eventually they reach a point at which the battery can no longer operate the equipment it is installed in for an adequate period.

High drain applications such as powertools may require the battery to be able to supply a current of 15C - 15 times C - the battery capacity in Ah, whereas MP3 players may only require 0.1C (discharging in 10 hours). With similar technology, the MP3 battery can tolerate a much higher internal resistance, so will have an effective life of many more cycles.[13]

Li-ion batteries can even go into a state that is known as deep discharge. At this point, the battery may take a very long time to recharge. For example, a laptop battery that normally charges fully in 3 hours may take up to 42 hours to recharge. Or the deep discharge state may be so severe that the battery will never come back to life. Deep discharging only takes place when products with rechargeable batteries are left unused for extended periods of time (often 2 or more years) or when they are recharged so often that they can no longer hold a charge. This makes Li-ion batteries unsuitable for back-up applications where they may become completely discharged.

A stand-alone Li-ion cell must never be discharged below a certain voltage to avoid irreversible damage. Therefore all Li-ion battery systems are equipped with a circuit that shuts down the system when the battery is discharged below the predefined threshold.[11] It should thus be impossible to "deep discharge" the battery in a properly designed system during normal use. This is also one of the reasons Li-ion cells are rarely sold as such to consumers, but only as finished batteries designed to fit a particular system.

When the voltage monitoring circuit is built inside the battery (a so-called "smart" battery) rather than the equipment, it continuously draws a small current from the battery even when the battery is not in use; furthermore, the battery must not be stored fully discharged for prolonged periods of time, to avoid damage due to deep discharge.

Li-ion batteries are not as durable as nickel metal hydride or nickel-cadmium designs and can be extremely dangerous if mistreated. They are usually more expensive.

Li-ion chemistry is not as safe as nickel metal hydride or nickel-cadmium, and a Li-ion cell requires several mandatory safety devices to be built in before it can be considered safe for use outside of a laboratory. These are: shut-down separator (for overtemperature), tear-away tab (for internal pressure), vent (pressure relief), and thermal interrupt (overcurrent/overcharging).[11] The devices take away useful space inside the cells, and add an additional layer of unreliability. Typically, their action is to permanently and irreversibly disable the cell.

Approximately 1% of Li-ion batteries are the subject of recalls. [14] (see Controversy).

The number of safety features can be compared with that of a nickel metal hydride cell, which only has a hydrogen/oxygen recombination device (preventing damage due to mild overcharging) and a back-up pressure valve.[citation needed]

 

[4BangR-x]

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[bartels903]

[edit] Lithium Cobalt Oxide Cathodes
Lithium ion batteries were first commercialized by Sony in 1991.[17] The cells utilized a lithium cobalt oxide cathode and a graphite anode. Sony and Sanyo are the leading producers of lithium ion batteries.[18][19] A variety of Chinese, Japanese, and South Korean companies produce cells based on the lithium cobalt oxide cathode chemistry.[20]


[edit] Manganese Spinel Cathodes
LG Chem, which is the third largest producer of lithium ion batteries, uses the lithium manganese spinel for its cathode. It is working with its subsidiary CPI to commercialize lithium ion batteries containing manganese spinel for HEV applications.[21] Several other companies are also working on manganese spinel, including NEC and Samsung.[22]


[edit] Lithium Iron Phosphate Cathodes
The University of Texas first licensed its patent for lithium iron phosphate cathodes to HydroQuebec.[23] Phostech was later spun-off from Hydroquebec for the sole development of lithium iron phosphate.

Valence Technology, located in Austin, TX, is also working on lithium iron phosphate cells. Since March 2005, the Segway Personal Transporter has been shipping with extended-range lithium-ion batteries[24] made by Valence Technology using iron phosphate cathode materials. Segway, Inc chose to build their large-format battery with this cathode material because of its improved safety over metal-oxide materials.

In November 2005, A123Systems announced[25] the development of lithium iron phosphate cells [26][27] based on research licensed from MIT. Although MIT and A123 initially claimed to have doped lithium iron phosphate in order to improve the material, it was later shown that this is not the case.[28] The improved performance was due to the presence of an electronically conductive network of carbon surrounding individual lithium iron phosphate particles. Because the original work on this cathode chemistry was done at the University of Texas, the patent licensed by A123 is under litigation. [29] While the battery has a lower energy density that other competing Lithium Ion technologies, a 2 Ahr cell can provide a peak of 70 Amps without damage, and operate at temperatures above 60 degrees C. Their first cell is in production (1Q/2006) and being used in consumer products including DeWalt power tools, aviation products, automotive hybrid systems and PHEV conversions.


[edit] Titanate Anodes
Altairnano,[30] a small firm based in Reno, Nevada, has announced a nano-sized titanate electrode material for lithium-ion batteries. It is claimed the prototype battery has three times the power output of existing batteries and can be fully charged in six minutes. However the energy capacity is about half that of normal li-ion cells. The company also says the battery can handle approximately 20,000 recharging cycles, so durability and battery life are much longer, estimated to be around 20 years or four times longer than regular lithium-ion batteries. The batteries can operate from -50 °C to over 75 °C and will not explode or result in thermal runaway even under severe conditions because they do not contain graphite-coated-metal anode electrode material.[31] The batteries are currently being tested in a new production car made by Phoenix Motorcars which was on display at the 2006 SEMA motorshow.

Enerdel, which is jointly owned by Ener1 and Delphi, is working to commercialize cells containing a titanate anode and manganese spinel cathode. [32] Although the cells show excellent thermal properties and cyclability, their low voltage may mitigate commercial success. [33]


All these formulations involve new electrodes (anodes or cathodes). By increasing the effective electrode area — thus decreasing the internal resistance of the battery — the current can be increased during both use and charging. This is similar to developments in ultracapacitors. Therefore, the battery is capable of delivering more power (watts); however, the battery's capacity (ampere-hours) is increased only slightly.


[edit] Breakthrough Research
In April 2006, a group of scientists at MIT announced a process which uses viruses to form nano-sized wires. These can be used to build ultrathin lithium-ion batteries with three times the normal energy density.[34]

As of June 2006, researchers in France have created nanostructured battery electrodes with several times the energy capacity, by weight and volume, of conventional electrodes.[35]


In December 2007, researchers at Stanford university reported creating a lithium ion battery with ten times the energy density (amount of energy available by weight) through using silicon nanowires deposited on stainless steel as the anode. The battery takes advantage of the fact that silicon can hold large amounts of lithium, and helps alleviate the longstanding problem of cracking by the small size of the wires. [1] To gain a 10fold improvement in energy density, the cathode would need to be improved as well; however, just improving the anode as such could provide a severalfold improvement in energy densitity. The team leader, Yi Cui, expects to be able to commercialize the technology in about five years.[2]


[edit] Guidelines for prolonging Li-ion battery life
Unlike Ni-Cd batteries, lithium-ion batteries should be charged early and often. However, if they are not used for a long time, they should be brought to a charge level of around 40% - 60%. Lithium-ion batteries should not be frequently fully discharged and recharged ("deep-cycled") like Ni-Cd batteries, but this is necessary after about every 30th recharge to recalibrate any external electronic "fuel gauge" (e.g. State Of Charge meter). This prevents the fuel gauge from showing an incorrect battery charge.[13]
Lithium-ion batteries should never be depleted to below their minimum voltage, 2.4v to 3.0v per cell.
Li-ion batteries should be kept cool. Ideally they are stored in a refrigerator. Aging will take its toll much faster at high temperatures. The high temperatures found in cars cause lithium-ion batteries to degrade rapidly.
According to one book,[36] lithium-ion batteries should not be frozen (most lithium-ion battery electrolytes freeze at approximately −40 °C; this is much colder than the lowest temperature reached by household freezers, however).
Li-ion batteries should be bought only when needed, because the aging process begins as soon as the battery is manufactured.[13]
When using a notebook computer running from fixed line power over extended periods, the battery should be removed,[37] and stored in a cool place so that it is not affected by the heat produced by the computer.

[edit] Storage temperature and charge
Storing a Li-ion battery at the correct temperature and charge makes all the difference in maintaining its storage capacity. The following table shows the amount of permanent capacity loss that will occur after storage at a given charge level and temperature.

Permanent Capacity Loss versus Storage Conditions Storage Temperature 40% Charge 100% Charge
0 °C (32 °F) 2% loss after 1 year 6% loss after 1 year
25 °C (77 °F) 4% loss after 1 year 20% loss after 1 year
40 °C (104 °F) 15% loss after 1 year 35% loss after 1 year
60 °C (140 °F) 25% loss after 1 year 40% loss after 3 months
Source: BatteryUniversity.com[13]
It is significantly beneficial to avoid storing a lithium-ion battery at full charge. A Li-ion battery stored at 40% charge will last many times longer than one stored at 100% charge, particularly at higher temperatures.[13]

If a Li-ion battery is stored with too low a charge, there is a risk of allowing the charge to drop below the battery's low-voltage threshold, resulting in an unrecoverably dead battery. Once the charge has dropped to this level, recharging it can be dangerous. Some batteries therefore feature an internal safety circuit which will prevent charging in this state, and the battery will be for all practical purposes dead.[citation needed]

In circumstances where a second Li-ion battery is available for a given device, it is recommended that the unused battery be discharged to 40% and placed in the refrigerator to prolong its shelf life. While the battery can be used or charged immediately, some Li-ion batteries will provide more energy when brought to room temperature.


[edit] Prolonging Life in Multiple Cells Through Cell Balancing
Analog front ends that balance cells and eliminate mismatches of cells in series or parallel significantly improve battery efficiency and increase the overall pack capacity. As the number of cells and load currents increase, the potential for mismatch also increases. There are two kinds of mismatch in the pack: State-of-Charge (SOC) and capacity/energy (C/E) mismatch. Though the SOC mismatch is more common, each problem limits the pack capacity (mAh) to the capacity of the weakest cell.

It is important to recognize that the cell mismatch results more from limitations in process control and inspection than from variations inherent in the Lithium Ion chemistry. The use of cell balancing can improve the performance of series connected Li-ion Cells by addressing both SOC and C/E issues.[38] SOC mismatch can be remedied by balancing the cell during an initial conditioning period and subsequently only during the charge phase. C/E mismatch remedies are more difficult to implement and harder to measure and require balancing during both charge and discharge periods.

Cell Balancing

Cell balancing is defined as the application of differential currents to individual cells (or combinations of cells) in a series string. Normally, of course, cells in a series string receive identical currents. A battery pack requires additional components and circuitry to achieve cell balancing. However, the use of a fully integrated analog front end for cell balancing[39] reduces the required external components to just balancing resistors.

This type of solution eliminates the need for discrete capacitors, diodes and most other resistors to achieve balance.

Battery pack cells are balanced when all the cells in the battery pack meet two conditions.

1. If all cells have the same capacity, then they are balanced when they have the same relative State of Charge (SOC.) In this case, the Open Circuit Voltage (OCV) is a good measure of the SOC. If, in an out of balance pack, all cells can be differentially charged to full capacity (balanced), then they will subsequently cycle normally without any additional adjustments. This is mostly a one shot fix.

2. If the cells have different capacities, they are also considered balanced when the SOC is the same. But, since SOC is a relative measure, the absolute amount of capacity for each cell is different. To keep the cells with different capacities at the same SOC, cell balancing must provide differential amounts of current to cells in the series string during both charge and discharge on every cycle.


[edit] Controversy

Dell laptop burnt by a defective Sony lithium-ion batteryLithium-ion batteries can rupture, ignite, or explode when exposed to high temperature environments, for example in an area that is prone to prolonged direct sunlight. [40]. Short-circuiting a Li-ion battery can cause it to ignite or explode, and as such, any attempt to open or modify a Li-ion battery's casing or circuitry is dangerous. Li-ion batteries contain safety devices that protect the cells inside from abuse, and, if damaged, can cause the battery to ignite or explode.

Contaminants inside the cells can defeat these safety devices. For example, the mid-2006 recall of approximately 10 million Sony batteries used in Dell, Sony, Apple, Lenovo/IBM, Panasonic, Toshiba, Hitachi, Fujitsu and Sharp laptops was stated to be as a consequence of internal contamination with metal particles. Under some circumstances, these can pierce the separator, causing the cell to short, rapidly converting all of the energy in the cell to heat[41]resulting in an exothermic oxidizing reaction (also known as "fire"), increasing the temperature to a few hundred degrees Celsius in a fraction of a second. This causes the neighbouring cells to heat up causing a chain thermal reaction. However, there are problems that go beyond this and so this explanation is not complete.

The mid-2006 Sony laptop battery recall was not the first of its kind, however it is the largest to date. During the past decade there have been numerous recalls of lithium-ion batteries in cellular phones and laptops owing to overheating problems. In October 2004, Kyocera Wireless recalled approximately 1 million batteries used in cellular phones, due to counterfeit batteries produced in Kyocera's name.[42] In December 2006, Dell recalled approximately 22,000 batteries from the U.S. market.[43] In March 2007, Lenovo recalled approximately 205,000 9-cell lithium-ion batteries due to an explosion risk. In August 2007, Nokia recalled over 46 million lithium-ion batteries, warning that some of them might overheat and possibly explode.[44] There was an incident in the Philippines involving a Nokia N91, which uses the BL-5C battery.[45]

It is possible to replace the lithium cobalt oxide cathode material in li-ion batteries with lithiated metal phosphate cathodes that are not as sensitive to temperature, and so are less prone to explode. This also extends their shelf life. However, currently these 'safer' li-ion batteries are mainly destined for electric cars and other large-capacity battery applications, where the safety issues are more critical. Unfortunately, a problem with these 'safer' li-ion batteries is that lithiated metal phosphate batteries hold only about 75 percent as much [energy].[46]

Another option is to use manganese oxide or iron phosphate cathode.[47]

 

[bartels903]

That is all for tonight. Ill add more tomorrow.

 

[4BangR-x]

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[Black91TSiAWD]

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[bartels903]

Batterys are good.

 

[EDM95]

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